Flame to Make Nanoparticles
FIRE!
The oldest known way to turn raw materials into useable goods. Today, scientists use a sophisticated version of the well known technique. Flame aerosol synthesis is being used to create nanoparticles. This process is very effective, but comes with significant challenges. First is flame manipulation, but also getting precise control over the distribution and size of nanoparticles. Lastly, of course, is cost.
The University of Buffalo is working on these issues. They have created a flame aerosol system that is versatile, easy to use and cheap. The study was published on October 30, in Nature Communications. It describes how scientists used the methodology to create metal-organic frameworks (MOFs). These are porous nanomaterials that are used in many fields, including the environment, health and medicine.
The study's lead author is named Mark Swihart, Ph.D. He is a SUNY Distinguished Professor and chair of the Department of Chemical and Biological Engineering in the UB School of Engineering and Applied Sciences. He reports, "This is, to the best of our knowledge, the first time that flame aerosol technology has been applied to create MOFs."
Almost all MOFs are made with a liquid chemical reaction. These are effective at making materials with a high degree of crystallinity. Making MOFs in this manner is expensive and time consuming. The flame aerosol system will be much faster and far less expensive. This is because it only requires one step. Flame MOFs have a lower porosity than conventional MOFs. They also have a small grain size, short-range ordered structures and high thermal stability. The findings could lead to new commercial uses!
The flame aerosol system circumvents thermodynamic barriers. Researchers claim that the mixing of any two metal elements into a single MOF is possible. The original articles on flame aerosol was published on August 27 in Matter. It expressed the potential for creating high-entropy ceramic nanomaterials. These nanomaterials are highly stable and made of multiple elements. They have unique properties, making them perfect for energy storage and sensing. Using the flame aerosol system, scientists created 22 elements. This demonstrated the flexibility of such applications.
Swihart summarizes, "The flame reactor is a scalable one step and incredibly versatile way to fabricate high-entropy nanoceramics, as well as other materials."

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